Chemical Properties of Carboxylic Acids and its Derivatives

IMPORTANT

Chemical Properties of Carboxylic Acids and its Derivatives: Overview

This topic covers concepts, such as, Chemical Properties of Carboxylic Acids, Reactions of Carboxylic Acids involving Cleavage of O-H Bond, Chemical Properties of Acid Chloride & Reduction of Acid Chlorides etc.

Important Questions on Chemical Properties of Carboxylic Acids and its Derivatives

MEDIUM
IMPORTANT

The correct increasing order of acidic strength of the following compounds is

(i) benzoic acid

(ii) 4-nitro benzoic acid

(iii)  3, 4-dinitrobenzoic acid

(iv) 4-methoxybenzoic acid

HARD
IMPORTANT

Identify A to D in the following sequences of operations:

 CH3CH2COOHΔNH3ABr2/KOH  BHONOC[O]CH3COOHDistilCa(OH)2D

MEDIUM
IMPORTANT

The reagents that can be used to distinguish between the following pairs of compounds would be:

(i) Propanal and Propanone

(ii) Phenol and Benzoic acid

EASY
IMPORTANT

Among the following acids which has the lowest  pKa value?

MEDIUM
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A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was:

EASY
IMPORTANT

A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was:

EASY
IMPORTANT

Which amongst the following compounds has the highest acid strength?

MEDIUM
IMPORTANT

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: A solution of the product obtained by heating a mole of glycine with a mole of chlorine in presence of red phosphorous generates chiral carbon atom.
Reason R: A molecule with 2 chiral carbons is always optically active.
In the light of above statements, chose the correct answer from the options given below: 

HARD
IMPORTANT

Match List-I with .

List-I

Name of reaction

List-II

Reagent used

A Hell-Volhard Zelinsky reaction I NaOH + I2
B Iodoform reaction II (i) CrO2Cl2, CS2 (ii) H2O
C Etard reaction III (i) Br2/red phosphorus(ii) H2O
D Gatterman-Koch reaction IV CO, HCl, anhyd. AlCl3

Choose the correct answer from the options given below:

MEDIUM
IMPORTANT

The reaction used for preparation of soap from fat is :

MEDIUM
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The major product formed in the following reaction is

Question Image

 

MEDIUM
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Compare the acid strength of:

1.o-flourobenzoic acid2.o-chlorobenzoic acid3.o-bromobenzoic acid4.o-iodobenzoic acid

HARD
IMPORTANT

Find the correct order of acidity of the following compounds :

Question Image

MEDIUM
IMPORTANT

Match the following

Name of the Reaction Reagents
(a) Etard reaction (p) NaOCl
(b) Iodoform (q) CO/HCl, Anhyd.AlCl3
(c) Gattermann (r) CrO2Cl2, CS2, H3O+
(d) HVZ (s) X2/Red P, H2O

MEDIUM
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State the name of the compound Question Image and name the acid and alcohol from which it is formed.

HARD
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Question Image.

What is the degree of unsaturation of A?

MEDIUM
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Which of the following compound is converted to an optical isomer when it is treated with Br2 in presence of red phosphorus?

HARD
IMPORTANT

Which of the following reagents can't be used for the reduction of CH3COOH to CH3CH2OH?

MEDIUM
IMPORTANT

For the following acids

CH33CCH2CO2HI    CH33N+CH2CO2H II   CH3-COOHIII

pKa values will be in the order

MEDIUM
IMPORTANT

In the given esterification rate of reaction maximum when

Question Image